ࡱ> `_ I@\p Rick Greene Ba= =hKL,8D@"1Arial1Arial1Arial1Arial1Arial1Arial1Arial1Arial1Arial1Helv"$"#,##0_);\("$"#,##0\)!"$"#,##0_);[Red]\("$"#,##0\)""$"#,##0.00_);\("$"#,##0.00\)'""$"#,##0.00_);[Red]\("$"#,##0.00\)7*2_("$"* #,##0_);_("$"* \(#,##0\);_("$"* "-"_);_(@_).))_(* #,##0_);_(* \(#,##0\);_(* "-"_);_(@_)?,:_("$"* #,##0.00_);_("$"* \(#,##0.00\);_("$"* "-"??_);_(@_)6+1_(* #,##0.00_);_(* \(#,##0.00\);_(* "-"??_);_(@_)0.0 0.00_)0_) 0.0_)                + ) , *       H " " ! ! !X   H   !X !  h  !T ! ! ! ! ! ! !     !  ! ! !P `>#Sample Description7Metals 29PCBs#u}Dioxins,Furan,Coplanar PCBs OC Pesticides Methods and QA`iR01SGDelaware EstuaryCherry Island Flats Striped BassFillet Skin OnR02SGR03SGR04SGR05SGC01SGC02SGC03SGC04SGC05SGR01BMid-Delaware Bay 39 00 00.9 75 11 08.8R02BR03BR04BR05BC01BC02BC03BC04BC05BBDelaware Department of Natural Resources and Environmental ControlRData and information in this spreadsheet were obtained from the following sources:Sample DescriptionMeanMinimumMaximumDatePortion No.of FishLengthWeight Sample ID WaterbodyLocationLatitude LongitudeSampledSpeciesAnalyzed in Sample(cm)(gm)Metals Results PCB Results$Concentrations are in ng/g (ppb) wet!Concentrations in pg/g (pptr) wet Organochlorine Pesticide Results Concentrations in ng/g (ppb) wet A. MethodsiOrganic contaminants were analyzed by the Midwest Research Institute (MRI) under contract with the DNREC.CLaboratory methods for organic contaminants are fully described in:)Briefly with regard to chemical analyses,}All other organic compounds were analyzed by High Resolution Gas Chromatography/Low Resolution Mass Spectrometry (HRGC/LRMS).B. Quality AssuranceQuality assurance procedures for organic analyses included method blanks, matrix spikes, matrix spike duplicates, and percent recoveries for internal standardsBand surrogate standards. Results of QA testing are documented in:DNREC 1992 Striped Bass Studyw1. Midwest Reseach Institute. 1993. Analysis of Fish Tissue Samples for Congener-Specific PCBs and Pesticides for v Assessing Pollutant Bioaccumulation from the Delaware Estuary (MRI Project No. 3123-01). Report prepared by thew Midwest Research Institute for the Delaware Department of Natural Resources and Environmental Control, Dover, DE.rMidwest Reseach Institute. 1993. Analysis of Fish Tissue Samples for Congener-Specific PCBs and Pesticides for pAssessing Pollutant Bioaccumulation from the Delaware Estuary (MRI Project No. 3123-01). Report prepared by theqMidwest Research Institute for the Delaware Department of Natural Resources and Environmental Control, Dover, DE.u2. Greene, R.W. and R.W. Miller. 1994. Summary and Assessment of Polychlorinated Biphenyls and Selected Pesticides& Environmental Control, Dover, DE.t in Striped Bass from the Delaware Estuary. Report prepared by the Delaware Department of Natural Resources and 3. DNREC Laboratory Data Files.Samples from the Cherry Island Flats were collected by the Delaware Department of Natural Resources and Environmental Control's Division of Fish and Wildlife.RProcedures for dissection, tissue grinding, and sample storage are described in: qGreene, R.W. and R.W. Miller. 1994. Summary and Assessment of Polychlorinated Biphenyls and Selected Pesticidesoin Striped Bass from the Delaware Estuary. Report prepared by the Delaware Department of Natural Resources and!Environmental Control, Dover, DE.CLaboratory analyses for metals were not performed on these samples.,A. PCB Congener Data, ng/g wet weight basisRO1SGRO2SGCO4SGRO1BCO1B Delaware BayMid-Bay% Lipid1 Mono U(1.24 cdl) U(1.25 cdl) U(1.23 cdl) U(2.48 cdl) U(1.20 cdl)U(2.46) U(1.21 cdl) U(1.22 cdl)U(1.38)3 Mono U(2.51 cdl)U(2.49)U(1.40)4 DiU(4.31)U(2.55)U(2.25) U(3.35 cdl)U(1.54)U(3.81)U(1.37)U(2.00)U(2.82)U(2.28)7 DiU(2.62)U(1.55) U(2.04 cdl)U(2.32)U(1.51)U(1.72)U(1.39)18 TriU(2.68)U(1.96)U(3.88)U(2.58)U(4.18)28 Tri U(2.47 cdl) U(2.46 cdl) U(2.40 cdl)44 Tetra U(2.49 cdl)52 Tetra74 Tetra87 Penta99 Penta 101 Penta 105 Penta 114 Penta U(2.44 cdl) U(2.42 cdl) U(2.50 cdl) U(2.43 cdl) U(2.45 cdl) U(2.39 cdl)118Penta 123 Penta U(2.07 cdl) U(2.06 cdl) U(2.05 cdl) U(1.99 cdl) U(2.03 cdl) U(2.02 cdl) U(2.08 cdl) U(2.00 cdl)128 Hexa137 Hexa 138/158Hexa153 Hexa156 Hexa157 Hexa U(2.38 cdl) U(2.37 cdl) U(2.31 cdl) U(2.35 cdl) U(2.33 cdl) U(2.34 cdl) U(2.30 cdl) U(2.41 cdl)166 Hexa167 Hexa168 Hexa U(2.14 cdl) 170/190 Hepta U(6.31 cdl) U(6.36 cdl) U(6.21 cdl) U(6.23 cdl) U(6.40 cdl) 180 Hepta 183 Hepta 185 Hepta U(3.72 cdl) U(3.74 cdl) U(3.69 cdl) U(3.71 cdl) U(3.60 cdl) U(3.66 cdl) U(3.63 cdl) U(3.65 cdl) U(3.68 cdl) U(3.59 cdl) U(3.75 cdl) U(3.64 cdl) U(3.70 cdl) 187 Hepta 189 Hepta 191 Hepta194 Octa199 Octa205 Octa207 Nona209 Deca U(6.09 cdl) U(6.13 cdl) U(3.58 cdl) U(6.19 cdl) U(6.01 cdl) U(6.17 cdl) U(6.08 cdl)Sum of CongenersNotes:^2. U(#)= Compound not detected. Value in parentheses is an instrumental noise detection limit.^1. U(#)= Compound not detected. Value in parentheses is an instrumental noise detection limit.1. U(# cdl) = Compound not detected. Value in parentheses is a calculated detection limit (cdl) based on the lowest calibration standard.U(1.24 cdl) (1) U(3.34) (2) +B. PCB Homolog Data, ng/g wet weight basis cis-Chlordanetrans-Chlordane U(2.60 cdl)Dieldrino,p'-DDDp,p'-DDDo,p'-DDEp,p'-DDEo,p'-DDTp,p'-DDT U(2.91) (2) U(2.48 cdl) (1) yCoplanar PCB congeners were analyzed by High Resolution Gas Chromatography/High Resolution Mass Spectrometry (HRGC/HRMS).Note: HRGC/HRMS analyses for dioxins and furans were not performed on these samples. HRGC/HRMS analyses for coplanar PCBs were performed on 4 8 of the 20 samples. Those results appear below..Dioxin/Furan and Coplanar PCB Congener Results77 Tetra78 Tetra79 Tetra80 Tetra81 Tetra 126 Penta 127 Penta 169 Hexa MNon-Ortho Coplanar PCB Raw Data, pg/g wet weight basis, analyzed by HRGC/HRMSU(2)U(2) (1) Note:MonoU(1.93)U(1.70) U(2.53 cdl)U(2.88)U(2.13)U(1.73)U(1.49)U(2.95)TetraPentaHexaHeptaOctaNonaDeca U(5.98 cdl)Di Tri Sum of Homologs U(3.26) (2) Samples from the Delaware Bay were obtained under special arrange from commercial shad fishermen who had caught striped bass as by-catch in their shad nets. 39 44 30.6 75 29 44.7} u0 t I  * ~ C1* { x L 3  I '^X3)mlG7MnM * {*! I@ )#07  dMbP?_*+%"??U} } m}  }  } }  }  } m } } } } );;       ?  @ A B F H G  I              ! 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