ࡱ>  I@\p Rick Greene Ba==X\+8@"1Arial1Arial1Arial1Arial1Arial1Arial1Arial1Arial1Arial"$"#,##0_);\("$"#,##0\)!"$"#,##0_);[Red]\("$"#,##0\)""$"#,##0.00_);\("$"#,##0.00\)'""$"#,##0.00_);[Red]\("$"#,##0.00\)7*2_("$"* #,##0_);_("$"* \(#,##0\);_("$"* "-"_);_(@_).))_(* #,##0_);_(* \(#,##0\);_(* "-"_);_(@_)?,:_("$"* #,##0.00_);_("$"* \(#,##0.00\);_("$"* "-"??_);_(@_)6+1_(* #,##0.00_);_(* \(#,##0.00\);_(* "-"??_);_(@_) mm/dd/yy0.0 0.000                + ) , *      " ! !  H " ! ! !X    !X !  h  H ! ! ! !P "T  D `C<Sample DescriptionXMetals )tPCBs$l Dioxins,Furans,Coplanar PCBs+E OC PesticidesPy OP PesticidesMethods and QA`i Z { Brandywine Tidal Reach Near Northeast Blvd. 39 44 33.7Channel CatfishFillet Skin Off ChristinaPool Below Smalley's DamnaLargemouth BassFillet Skin OnChurchman's RoadMouth of Churchman's Marsh 39 41 43.9Rittenhouse Park White Sucker Nonsuch Creek Route 141 Black Crappie&Tidal Reach 0.5 mi West of Hershey Run 39 42 00.3 Army CreekRoute 9Carp Broadkill Below Milton Dragon RunRoad 378 AppoquiniminkNoxontown PondBrown Bullhead C & D CanalRoute 13 Route 896BDelaware Department of Natural Resources and Environmental ControlMeanMinimumMaximumDatePortion No.of FishLengthWeight Sample ID WaterbodyLocationLatitude LongitudeSampledSpeciesAnalyzed in Sample(cm)(gm)RData and information in this spreadsheet were obtained from the following sources: 75 32 12.8 75 37 22.1 75 38 00.92. Midwest Research Institute. 1998. Analysis of Fish Tissue Samples for PCDDs, PCDFs, Congener-Specific PCBs, and Pesticides from the Chesapeake and Delaware Canal, Final Report (MRI Project No. 4875). Report prepared by the Midwest Research Institute\ for the Delaware Department of Natural Resources and Environmental Control, Dover, DE. 3. Greene, R.W. 1999. Chemical Contaminants in Finfish from the Chesapeake & Delaware Canal and Implications to Human Healthr Risk. Report prepared by the Delaware Department of Natural Resources and Environmental Control, Dover, DE. 4. DNREC Laboratory Data Files.Metals Results&Concentrations are in units of ppm wet PCB Results$Concentrations are in ng/g (ppb) wet!Concentrations in pg/g (pptr) wetGA. Dioxin/Furan Raw Data, pg/g wet weight basis, analyzed by HRGC/HRMS Organochlorine Pesticide Results Concentrations in ng/g (ppb) wet A. MethodsiSamples were collected by the Delaware Department of Natural Resources and Environmental Control (DNREC).TMetals were analyzed by the DNREC's Environmental Services Section (ESS) Laboratory.iOrganic contaminants were analyzed by the Midwest Research Institute (MRI) under contract with the DNREC.Field procedures for sample collection followed DNREC ESS Standard Operating Procedure No. 500 ("Field Procedures for Fish Sample Handling").Procedures for dissection, tissue grinding, and sample storage followed DNREC ESS Standard Operating Procedure No. 501 ("Processing of Finfish for Chemical Analyis"). WLaboratory methods for metals are described in DNREC ESS Standard Operating Procedures.CLaboratory methods for organic contaminants are fully described in:)Briefly with regard to chemical analyses,Metals other than mercury and zinc were analyzed using Graphite Furnace Atomic Absorption (GFAA). Zinc was analyzed using Inductively Coupled Argon Plasma (ICAP).LMercury was analyzed using Cold Vapor Atomic Absorption Spectrometry (CVAA).Dioxins, furans, and coplanar PCB congeners were analyzed by High Resolution Gas Chromatography/High Resolution Mass Spectrometry (HRGC/HRMS).}All other organic compounds were analyzed by High Resolution Gas Chromatography/Low Resolution Mass Spectrometry (HRGC/LRMS).B. Quality AssuranceQuality assurance testing for metals included matrix spike and matrix spike duplicate analyses. Results of those analyses are on file at the DNREC ESS Laboratory.Quality assurance procedures for organic analyses included method blanks, matrix spikes, matrix spike duplicates, and percent recoveries for internal standardsBand surrogate standards. Results of QA testing are documented in:Arsenic Cadmium Copper Lead MercurySeleniumZinc (ppm)< 0.2< 0.02 0.63< 0.12 0.04 8.75 0.32 0.25 7.9 0.54 0.13 0.03 8.16 6.1 0.43 0.28 11.5 0.24 0.3 8.99 0.27 0.05 6.36 0.02 20.4 0.39 0.12 7.69 0.34 0.46 18.5 0.2 4.86 0.29 0.22 4.1 0.26 0.35 0.06 9.64 0.42 5.57 0.33 4.88 8.18 0.41 6.44 5.86 0.4 0.14 8.1 0.74 6.95 0.23 5.11 0.36 0.1 8.44 0.44 5.15 4.78 5,A. PCB Congener Data, ng/g wet weight basis% Lipid Nonesuch Cr. White Clay Tidal ReachCatfishDiPCB(8)U(1.25) TriPCB(18) TriPCB(28) TriPCB(37) TetraPCB(42) TetraPCB(44) TetraPCB(47) TetraPCB(49) TetraPCB(52) TetraPCB(60) TetraPCB(64) TetraPCB(66) TetraPCB(70) TetraPCB(74) TetraPCB(80) PentaPCB(82)PentaPCB(84/101) PentaPCB(86) PentaPCB(87) PentaPCB(91) PentaPCB(92) PentaPCB(95) PentaPCB(97) PentaPCB(99)PentaPCB(105/127) PentaPCB(110) PentaPCB(114) PentaPCB(118) PentaPCB(119) PentaPCB(120) PentaPCB(123)HexaPCB(128/167) HexaPCB(137) HexaPCB(138) HexaPCB(141) HexaPCB(146) HexaPCB(149) HexaPCB(151) HexaPCB(153) HexaPCB(156) HexaPCB(157) HexaPCB(158) HexaPCB(166) HexaPCB(168)HeptaPCB(170/190) HeptaPCB(171) HeptaPCB(174) HeptaPCB(177) HeptaPCB(179) HeptaPCB(180) Hepta(183) HeptaPCB(185) HeptaPCB(187) HeptaPCB(189) HeptaPCB(191) OctaPCB(194) OctaPCB(195)OctaPCB(196/203) OctaPCB(198) OctaPCB(200) OctaPCB(201) OctaPCB(205) NonaPCB(206) NonaPCB(207) NonaPCB(208) DecaPCB(209)Sum of Congeners C&D CanalChannel Pool below Smalleys PondRoute 141, Basin Road Lgmouth BassNotes:U(2.5) U(1.25) (1) \1. U(#) = Compound not detected. Value in parentheses is the instrumental detection limit. +B. PCB Homolog Data, ng/g wet weight basisMonoDiTriTetraPentaHexaHeptaOctaNonaDecaSum of HomologsU(0.310)U(0.364)U(0.661)U(0.271) 2,3,7,8-TCDDU(0.088)1,2,3,7,8-PeCDF2,3,4,7,8-PeCDFU(0.685)U(0.279)U(0.353) U(0.0515)1,2,3,7,8-PeCDD U(0.0735)1,2,3,4,7,8-HxCDFU(0.184)1,2,3,6,7,8-HxCDF2,3,4,6,7,8-HxCDFU(0.758) U(0.0860)U(0.193)U(0.236) U(0.0279)1,2,3,7,8,9-HxCDFU(0.304)U(0.860)U(0.238) U(0.0373)U(0.219)U(0.268) U(0.0517) U(0.0726) U(0.0317) U(0.0529)1,2,3,4,7,8-HxCDDU(0.414)U(0.265) U(0.0150)1,2,3,6,7,8-HxCDD1,2,3,7,8,9-HxCDDU(0.417)U(0.267) U(0.0152)1,2,3,4,6,7,8-HpCDFU(0.405) U(0.0508)1,2,3,4,7,8,9-HpCDFU(0.722)U(0.473)U(0.512)U(0.477)U(0.220)U(0.189)U(0.645)U(0.274)U(0.191)U(0.148) U(0.0599)1,2,3,4,6,7,8-HpCDDOCDFOCDD Total TCDF Total TCDD U(0.0777) U(0.0776) U(0.00320) U(0.0853) U(0.0714) U(0.0421) U(0.0868) Total PECDFU(0.297) Total PECDDU(0.126)U(0.149) Total HXCDF Total HXCDD Total HPCDFU(0.663)U(0.435)U(0.470)U(0.438)U(0.174)U(0.592)U(0.175) Total HPCDD77-TCB81-TCB126-PeCB169-HxCBU(0.798)QB. Non-Ortho Coplanar PCB Raw Data, pg/g wet weight basis, analyzed by HRGC/HRMS U( .0266)U( .256) U( .0285)U( .379) U( .0243) U( .0276) U( .0298)U( .388)U( .283) U( .0576) U( .0216) U( .0332)U( .413)U( .026) U( .0305)U( .367)U( .514)U( 1.11)U( .238)U( .112)U( 2.59)U( 6.12)U( 43.2)U( 5.68)U( .26)U( .764)U(0.108)U( .182)U( .286)U( 1.47)U( .265)U( .334)U( .244)U( .207)U( .121) U( .0937)U( 1.54) U( .0657)U( .111) U( .0798)U( .103)U( 3.96) U( 7.73E-03)U( 27.2)U( 2.72)U( .141)0.713JU(10)Sum of DDD,DDE,DDT cis-Chlordane trans-Chlordane cis- Nonachlortrans- Nonachlor OxychlordaneSum of Chlordanes: DicofolDieldrin Endosulfan I Endosulfan IIEndrinHeptachlor EpoxideHexachlorobenzeneLindaneMirex OxyfluorfenTurbufosDiazinon Disulfoton ChlorpyrifosEthionCarbophenothion U( 1.78 empc) U( .992 empc) U( .758 empc) U( .534 empc) U( .659 empc) U( 2.03 empc) U( 1.52 empc) U( 2.39 empc) U( 2.16 empc) U( 2.52 empc) U( 1.25 empc) U( 2.28 empc) U( 2.15 empc) U( .673 empc) U( 54.1 empc) U( 39.1 empc)U( .0833 empc) U( .243 empc) U( .554 empc) U( .982 empc) U( .493 empc) U( .237 empc) U( .646 empc) U( .178 empc)U( .0672 <empc) U( .559 empc) U( .325 empc) U( .518 empc) U( 1.85 empc) U( 1.64 empc) U( .215 empc) U( .109 empc) U( .435 empc) U( .223 empc) U( .385 empc) U( .34 empc) U( .442 empc) U( .37 empc)U( 1.22) U( .644 empc) U( .744 empc) U( 1.18 empc) U(.539 empc) U( .242 empc) U( .356 empc)2,3,7,8-TCDF (1) Y1. U(#)=Compound not detected. Value in parentheses is the instrumental detection limit. U(0.776 empc) U(0.811 empc) U(0.489 empc) U(47.9 empc) U(0.562 empc) U(0.259 empc) U(1.12 empc) U(0.188 empc) U(0.121 empc) U(0.087 empc) U(0.166 empc) U(0.480 empc) U(0.248 empc) U(0.438 empc) U(0.500 empc) U(1.14 empc) U(0.287 empc) U(0.115 empc) U(0.427 empc) U(0.164 empc) U(0.344 empc) U(0.175 empc) U(0.108 empc) U(0.389 empc) U(0.239 empc) U(0.206 empc)`1. TCDF should be considered a maximium because the DB-5 column is not specific for this isomer Y2. U(#)=Compound not detected. Value in parentheses is the instrumental detection limit.3. U(# empc)=Compound not detected. Value in parentheses is an estimated maximum possible concentration (empc) detection limit. U(0.799) (2) U(0.417 empc) (3) U(2.14 empc&) U(1.81 empc&) U(2.91 empc&) U(1.54 empc&) U(5.59 empc&) U(1.92 empc&) U(2.57 empc&)U(0.379 empc&)U(0.247 empc&) U(1.14 empc&) U(39.2 empc&) U(102 empc&) U(29.8 empc&) U(41.2 empc&) U(4.14 empc&) U(10.4 empc&) U(66.0 empc&) U(15.1 empc&) U(9.66 empc&) U(3.80 empc&) U(2.62 empc&) U(111 empc&) U(51.5 empc&)U(4.58 empc&) (4) 4. U(# empc&)=Compound not detected. Value in parentheses is an estimated maximum possible concentration (empc) detection limit based on a possible diphenyl ether interference.U( 3.47 empc&)U( 4.63 empc&)U( 1.79 empc&)U( 39.4 empc&)U( .612 empc&)U( 8.09 empc&)U( 10.5 empc&)U( 3.59 empc&) U( 112 empc&) U( .78 empc&)U( 2.52 empc&) U( 3 empc&)U( 35.8 empc&)U( 6.38 empc&)U( 5.56 empc&)U( 77.5 empc&)U( 1.28 empc&)U( 6.17 empc&) U(5.09 empc&)U( 72.8 empc&)U( .531 empc&)U( 2.47 empc&)U( 6.39 empc&)U( 4.81 empc&)U( 62.3 empc&)U( .863 empc&)U( 1.85 empc&)U( 4.52 empc&)U( 6.84 empc&)U( 54.8 empc&)U( .567 empc&) U( 1.8 empc&)U( 10.3 empc&)U( 7.13 empc&)U( 3.91 empc&) U( 143 empc&)U( .583 empc&)U( 2.74 empc&)U( 6.52 empc&)U( 3.96 empc&)U( 2.24 empc&)U( 71.6 empc&)U( .353 empc&)U( 5.06 empc&)U( 1.43 empc&)U( 20.1 empc&)U( 43.9 empc&)U( .555 empc&)U( 5.86 empc&)U( 4.46 empc&)U( 80.8 empc&) U( 185 empc&)U( 11.7 empc&)U( 5.13 empc&)U( 1.26 empc&)U( 20.6 empc&)U( 40.6 empc&)U( .603 empc&)U( 3.19 empc&)U( 1.63 empc&)U( 1.11 empc&)U( 14.8 empc&) U( 8 empc&)U( 4.73 empc&) U( 17 empc&) U(0.732) (1) U( 2.38 empc&) (5) U( .0411) (5) 0.964 (5) U( 33.2 empc&) (5) U( 9.68) (5) U( 2.61 empc) (5) U( 6.91) (5) j5. J=Value calculated from a 13C labelled internal quantitation standard with recovery outside of 25-150%.+Organophosphorus Pesticides and OxyfluorfenNote:v1. U(#)= Compound not detected. Value in parentheses is the detection limit based on the lowest calibration standard.U(<5)U(<50) U(10) (1) ToxapheneU(200)1. Midwest Reseach Institute. 1998. Analysis of Fish Tissue Samples for PCDDs, PCDFs, Congener-Specific PCBs, and Pesticides from Selected Delaware Stream Basins, FY '97 Final Report (MRI Project No. 4783). 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